ReproSil Chiral-MIB

Immobilized Cellulose-Based Chiral Phase with Tris-(3,5-dimethylphenyl)carbamate for Enantioselective Normal-Phase Chromatography

ReproSil Chiral-MIB is a silica-based HPLC stationary phase with immobilized tris-(3,5-dimethylphenyl)carbamate cellulose, developed for enantioselective separations under normal-phase conditions. The immobilized cellulose derivative provides strong and broad chiral recognition through hydrogen bonding, π–π interactions, dipole–dipole forces, and steric complementarity, enabling high-resolution separations for a wide range of racemic compounds.

Unlike conventional coated cellulose-based chiral phases, ReproSil Chiral-MIB features a covalently immobilized chiral selector, ensuring exceptional chemical and mechanical stability. This immobilization allows the use of a wider range of mobile phases, including polar or non-standard solvents, without compromising the phase’s chiral recognition performance. As a result, it provides greater flexibility and reliability for method development and robust enantioseparation workflows. Built on high-purity spherical silica, the phase exhibits excellent column efficiency, reproducible retention, and long operational lifetime. ReproSil Chiral-MIB is ideally suited for pharmaceutical, chemical, and biochemical applications, offering consistent and accurate enantioseparations in both analytical and preparative scales.

ReproSil Chiral-MIB combines the proven chiral recognition power of cellulose tris-(3,5-dimethylphenyl)carbamate with the durability of immobilized silica technology – the reliable choice for precise, flexible, and reproducible enantioselective separations in normal-phase chromatography.

Attractive alternative to CHIRALPAK® IB (Daicel®) and YMC Cellulose-SB (YMC).

For the use of our ReproSil Chiral-MIB columns, please refer to our Column Care Guide.

Key Features:

  • Silica-based stationary phase with immobilized tris-(3,5-dimethylphenyl)carbamate cellulose

  • Designed for enantioselective separations under normal-phase conditions

  • Strong chiral recognition via hydrogen bonding, π–π, and dipole–dipole interactions

  • Immobilized coating for enhanced chemical robustness and solvent compatibility

  • High-purity spherical silica for mechanical stability and reproducibility

  • Suitable for analytical and preparative chiral HPLC applications

Typical Applications:

  • Enantioselective separation of pharmaceuticals, intermediates, and fine chemicals

  • Method development requiring polar or mixed mobile phases

  • Routine chiral screening and optimization in pharmaceutical and chemical analysis

  • Quality control and stereochemical purity determination in research and production

Specifications

Request Product
Particle Sizes
  • 5 µm
  • 10 µm
Pore Size 1 000 Å
Surface Area 30 m²/g
Phase/Modification Tris-(3,5-dimethylphenyl)carbamat-Cellulose
Particle Type
Separation Modes
Endcapping No
pH Range 2 to 8

Material Numbers

Phase Material Number
ReproSil Chiral-MIB, 5 µm r65.mib.
ReproSil Chiral-MIB, 10 µm r60.mib.
ReproSil Chiral-MIA ReproSil Chiral-MIC

Any questions?
We are here to help you.

info@dr-maisch.com +49 7073 5035 7

Follow us